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You shut that shit down. You'll find it next to me. Whatever it is I got is clearly appealin'. Seems to push them away. I really can't see the end getting any closer. 15 of Drake's catchiest and most relatable lyrics about life. Uh, damn, I think you caught me in a moment. I just thought you would choose some where that had somebody that you know. Cause while all of my closest friends out partying. You know its real when yo' latest nights are yo' greatest nights.
Because all this shit is new to me, I'm learning to behave, And still spending every dollar they encourage me to save, but I'm good. Let's stay together 'til we're ghosts. CJ got my credit cards and a lot of ones. Yeah, that shit is pointless They told me not to fall in love, that shit is pointless. I can be (I can be). Got me on tour actin like I'm not that curious.
Say she miss the golds in my teeth / 4L s**t, know we steppin', y'all should get to funeral preparin'. And get what you been missing. Y'all know them, well f*ck it me either. Feel you've reached this message in error? Birdman go brrr 'cause he know this shit retarded. I haven't slept in days, and me and my latest girl agreed to go our seperate ways, so I'm single. Japanese Bonus Track). The always tell me no one is working as hard as you. Text me on the signal, don't call me. Drake tell your friends lyrics weeknd. Here's what a few lyrics from the song 'Major Distribution' really mean.
My n***** go in-Zayn to catch a body, we was face to face, you could've shot me. Bitch we good-fellas, boy all them niggas with you they just pall bearers. Yeah I try to tell them don't judge me because you heard stuff. Pain hurts like a cut from a beautiful knife. But if I really do it don't expect to get a split. I told my girl you can get it. And you know I'll be over there. I'm still rocking camo, I still roll with shooters. All I see is fireworks (ohh). Yup) I'll be over there. Bracelet saying you should quit. What we doing right now. Into women that are ready to get married at hello. Drake & 21 Savage 'Major Distribution' lyrics meaning revealed. Claiming I'm just not as serious as you.
Or from the SoundCloud app. I hope that my success never alters our relationship. Bitches will buy it for the picture. Young Money, stay young I been Cash Money since day one, Tunechi. And you do dinners at French Laundry in Napa Valley. Your the baddest girl around. And all the bad ones I used to hit her friends now. They would do it just like I do if they could. Never forgettin' from where I came, And no matter where I'm headed, I promise to stay the same. Yo, if Drizzy say "get her", I'm a get her. Down, down, down tryna lay you down, you still the baddest girl around, Round, round and they notice they notice you'll shut it. Enjoy the seat that the steward just forced your ass to let up. Hmm, hmm, in this mansion, I'm Macaulay Culkin. Drake tell your friends lyrics chords. So they tell me that they love me I know better than that it's just game.
That's when you start to laugh. You can run an tell my city it's on. But shit, you 'bout to spend it on what matters most. I've been up for 4 days. Drake tell your friends lyrics official. Savage still let his gun pop, FOX 5 gang, get you knocked. This lyric also has another meaning - 'Paid in Full' is a 2002 crime drama film which starred Mekhi Phifer. October's Own, but it's lookin' like July 4. Ask your girl, I'm the realest nigga she been around. I'm out here messin over the lives of these niggaz.
Where you record with two others that want the same things. Beat the pussy up, call me Larry Holmes. Mature women with more than me were the first to tempt me. Except the niggas that I came with, they good for life. I'm in love with Houston, Dallas, Austin. I'm allergic to comin in second. On "Fancy, " Drake gets some cool points for making an anthem dedicated to women who are focused on their own grinds. Time is on me, unforgettable. This prophetic lyric is clearly what we all feel about the people surrounding us in our lives. Tell Your Friends Paroles – DRAKE – GreatSong. Super good smito a package of the swishas. In disguise in the form of a favor.
Me and my Lamar would rob a nigga for his Jordans. How long they choose to love you will never be your decision. That was just a keep sake. Season switchin over, I come through them bitches. "I just take my time with all this shit, I still believe in that/ I had someone tell me I fell off, ooh, I needed that". Singing bout poppin pills, fucking bitches, living life so trill. Presidential suite girl Barrack Hussain. Bigger than you ever done it. I keep thinking how young can you die from old age.
If there's anythin I should know. I mean we don't even rock them shoes if it ain't got a comma on the price tag. And I swear I got this shit that makes these bitches go insane.
For example, pyrrole reacts with acetic anhydride or acetyl chloride and triethyl amine to give N-acetylpyrrole. There are seven diatomic elements: hydrogen, nitrogen, oxygen, fluorine, chlorine, iodine, bromine. Since the basic unshared electron pair is not part of the aromatic sextet, as in pyrrole, pyridinium species produced by N-substitution retain the aromaticity of pyridine. And when accidents do happen, space travellers can rely on fluorocarbon-based fire extinguishers to put the flames out. The α-lactone intermediate shown in the solvolysis of optically active 2-bromopropanoic acid (example 9) accounts both for the 1st-order kinetics of this reaction and the retention of configuration in the product.
Several examples of these stable and easily handled reagents are shown at the bottom of the diagram. Shows the structure of a feather without any coloration. When numbering a ring with more than one heteroatom, the highest priority atom is #1 and continues in the direction that gives the next priority atom the lowest number. What Are the 7 Diatomic Elements?
As noted for benzene and its derivatives, these substitutions take place by an initial electrophile addition, followed by a proton loss from the "onium" intermediate to regenerate the aromatic ring. Hydrogen is often evolved in the course of these reactions. The initial ring opening is stereoelectronically directed in a trans-diaxial fashion, the intermediate relaxing to the diequatorial conformer before cyclizing to a 1, 3-oxathiolane intermediate. 1 Compounds Containing Sulfur. Feathers have similar keratins and are extremely resistant to protein digestive enzymes. The fused ring heterocycles quinoline and isoquinoline provide additional evidence for the stability of the pyridine ring. Fluoride is an essential ion for animals, strengthening teeth and bones. A short list of some common prefixes is given in the following table, priority order increasing from right to left. Periodic Table of Videos, accessed December 2014. Reactions of pyrrole require careful evaluation, since N-protonation destroys its aromatic character. This is a controlling factor in the relatively facile nitration at C-4.
It is the most reactive of all the elements and quickly attacks all metals. Thank you also to Kira Weismann from Zaarland University in Germany. Note that two inversions of configuration at C-2 result in overall retention. Indeed, once one understands the ortho-para and meta-directing character of these substituents, their directing influence on heterocyclic ring substitution is not difficult to predict. How to Remember the Diatomic Elements The elements ending with "-gen" including halogens form diatomic molecules. It is also used for cable insulation, for plumber's tape and as the basis of Gore-Tex® (used in waterproof shoes and clothing). However, some scientists predict tennessine may behave more like a noble gas. Moreover, common mnemonics for the symptomatology of organophosphate poisoning, including sarin gas, are the "killer B's" of bronchorrhea and bronchospasm because they are the leading cause of death, and SLUDGE – salivation, lacrimation, urination, defecation, gastrointestinal distress, and emesis. Pyridine is a modest base (pKa=5. As before, common names are in black and systematic names in blue. Transcript: Chemistry in its element: fluorine. However, if the oxygen is bonded to an electrophile such as SO3, the resulting pyridinium ion will react sluggishly and preferentially at C-3.
Key Takeaways: Diatomic Elements Diatomic elements are pure elements that form molecules consisting of two atoms bonded together. Many compounds are diatomic, such as HCl, NaCl, and KBr. Example 5 is an interesting case of intramolecular rearrangement to an ortho-ester. Robbed of their co-factors, critical metabolic enzymes can no longer function, cells begin to die, tissues to liquefy and bone to corrode away. Because the flip side of fluorine's extreme reactivity is the strength of the bonds it forms with other atoms, notably including carbon.
Xanthine and uric acid are products of the metabolic oxidation of purines. Many other procedures leading to substituted heterocycles of this kind have been devised. Elements 1-112, 114, 116 and 117 © John Emsley 2012. The following diagram shows seven such reactions. Mustard agents could be deployed on the battlefield by means of artillery shells, aerial bombs, rockets, or by spraying from warplanes.
93 moles F. The ratio 3. Astatine has found uses in medicine even though it is radioactive and decays quickly. Moissan's feat earned him the 1906 Nobel Prize in chemistry, but the celebration was short-lived. The second presumably takes place by formation of a dianionic species in which the ArCH2 (–) unit bonds to the deactivated carbonyl group. Reactions 6 and 7 show alkylation and condensation reactions resulting from this activation. Other Reactions of Pyridine.
So you can run on a rainy day, and still stay dry. Thiols, disulfides, thioethers, and thioesters are common in biological compounds. In the environment fluorine cannot be destroyed; it can only change form. Depicts a generic equation for the formation of a disulfide from two thiol molecules. Shows a permanent hair-style. He took the normal precaution in such situations, quickly dowsing himself with water from a laboratory hose, and even plunged into a nearby swimming pool while the paramedics were en route. It occurs naturally as a minor component of petroleum, and is commonly added to otherwise odorless gaseous products such as liquefied petroleum gas (LPG), at very low doses, to help warn of gas leaks.
Reagents that affect the making and breaking of S–S bonds are key, e. g., ammonium thioglycolate. The rules for using this system will be given later. Halogens share many similar properties including: They all form acids when combined with hydrogen. ATP is the main source of energy that keeps your cells alive and functioning. At first glance, the sp3 hybridized nitrogen might appear to be the stronger base, but it should be remembered that N, N-dimethylaniline has a pKa slightly lower than that of pyridine itself. 8 g is F. Since the molar mass of F is 19, this is 3. Despite the fact that fluorine and chlorine are poisonous, small amounts are essential to human health and life. The empirical formula must be SF5, according to a typical analysis. A similar intermediate may be written for substitution of a 4-halopyridine, but substitution at the 3-position is prohibited by the the failure to create an intermediate of this kind. Due to its use in previous studies, the nitrogen mustard called "HN2", later known as mustine, became the first cancer chemotherapy drug to be used. The reaction conditions show clearly the greater reactivity of furan compared with thiophene. 788 mole S. The remaining 74. Science, Tech, Math › Science What Are the 7 Diatomic Elements? The corresponding values for the saturated amine pyrrolidine are: basicity 11.